Main Article Content
Abstract
A rapid, non-destructive and reagent-free infrared spectroscopy combined with Partial Least Square (PLS) has been developed for the dexamethasone quantification in joint-pain killer traditional herbal medicine (THM). The main aim of this study is to select the best wavenumbers that are capable of providing the high coefficient of determination (R2), low values of Root Mean Square Error of Calibration (RMSEC), Root Mean Square Error of Cross Validation (RMSECV) and predictive residual error sum of squares (PRESS). Finally, wavenumbers 3646, 3642, 2461, 2453, 2432, 2406, 2229, 2209, 2197, 2097, 2092, 2064, 2059, 2047, 2026, 2009, 1969, and 1513 cm-1 were selected for the prediction of dexamethasone in the joint-pain killer traditional herbal medicine. The correlation between the actual values of dexamethasone determined in joint-pain killer traditional herbal medicine using infrared spectroscopy combined with PLS revealed the R2 values of 0.9988. The RMSEC values obtained 0,009455. The PRESS and RMSECV value obtained as the results of cross-validation model selection for dexamethasone in joint-pain killer traditional herbal medicine were 0,0022721.00 and 0,02902, respectively. The high value of R2 and low value of RMSEC, RMSECV and PRESS indicated that this method had high accuracy and precision in a validated condition for the dexamethasone quantification in the joint-pain killer traditional herbal medicine. These results indicated that infrared spectroscopy combined with PLS can be an alternative method for the dexamethasone determination in joint-pain killer traditional herbal medicine.his part contains English version of the abstract. The abstract presents background, method of the research/ literary study and discussion. The abstract consist of maximum 300 words. All sentence must represent the core of research presented in good structure of sentences.
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References
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References
Brereton, R.G., 2000. Introduction to multivariate calibration in analytical chemistry. Analyst 125, 2125–2154.
Cebi, N., Yilmaz, M.T., Sagdic, O., 2017. A rapid ATR-FTIR spectroscopic method for detection of sibutramine adulteration in tea and coffee based on hierarchical cluster and principal component analyses. Food Chem. 229, 517–526.
Chen, J., Zhou, Q., Sun, S., 2016. Adulteration screening of botanical materials by a sensitive and model-free approach using infrared spectroscopic imaging and two-dimensional correlation infrared spectroscopy. J. Mol. Struct., Special Issue: Novel Developments and Applications of Two-Dimensional Correlation Spectroscopy 1124, 262–267.
Cho, S.-H., Park, H.J., Lee, J.H., Kim, H.J., Cho, S., Yoon, C.-Y., Kim, W.S., 2014. Monitoring of 35 illegally added steroid compounds in foods and dietary supplements. Food Addit. Contam. Part A 31, 1470–1475.
Curtis, J.R., Westfall, A.O., Allison, J., Bijlsma, J.W., Freeman, A., George, V., Kovac, S.H., Spettell, C.M., Saag, K.G., 2006. Population-based assessment of adverse events associated with long-term glucocorticoid use. Arthritis Care Res. 55, 420–426.
Faber, N.M., Rajk, R., 2007. How to avoid over-fitting in multivariate calibration: The Conventional Validation Approach and an Alternative. Anal. Chim. Acta 595, 98–106.
Hoes, J.N., Jacobs, J.W.G., Verstappen, S.M.M., Bijlsma, J.W.J., Van der Heijden, G., 2009. Adverse events of low-to medium-dose oral glucocorticoids in inflammatory diseases: a meta-analysis. Ann. Rheum. Dis. 68, 1833–1838.
Jin, P., Liang, X., Wu, X., He, X., Kuang, Y., Hu, X., 2018. Screening and quantification of 18 glucocorticoid adulterants from herbal pharmaceuticals and health foods by HPLC and confirmed by LC-Q-TOF-MS/MS. Food Addit. Contam. Part A 35, 10–19.
Moros, J., Garrigues, S., Guardia, M. de la, 2010. Vibrational spectroscopy provides a green tool for multi-component analysis. TrAC Trends Anal. Chem. 29, 578–591.
Mukherjee, P.K., Houghton, P.J., 2009. Evaluation of herbal medicinal products: perspectives on quality, safety, and efficacy. Pharmaceutical Press, London?; Chicago.
Poetker, D.M., Reh, D.D., 2010. A comprehensive review of the adverse effects of systemic corticosteroids. Otolaryngol. Clin. North Am. 43, 753–768.
Rohman, A., 2013. Application of fourier transform infrared spectroscopy for quality control of pharmaceutical products. Indones. J. Pharm. 23, 1–8.
Rohman, A., . S., . D., Ramadhani, D., Nugroho, A., 2015. Analysis of Curcumin in Curcuma longa and Curcuma xanthorriza Using FTIR Spectroscopy and Chemometrics. Res. J. Med. Plant 9, 179–186.
Rohman, A., Che Man, Y.B., 2012. Quantification and Classification of Corn and Sunflower Oils as Adulterants in Olive Oil Using Chemometrics and FTIR Spectra. Sci. World J. 2012.
Rohman, A., Man, Y.B.C., 2010. Fourier transform infrared (FTIR) spectroscopy for analysis of extra virgin olive oil adulterated with palm oil. Food Res. Int. 43, 886–892.
Rooney, J.S., McDowell, A., Strachan, C.J., Gordon, K.C., 2015. Evaluation of vibrational spectroscopic methods to identify and quantify multiple adulterants in herbal medicines. Talanta 138, 77–85.
Sanzini, E., Badea, M., Santos, A.D., Restani, P., Sievers, H., 2011. Quality control of plant food supplements. Food Funct. 2, 740–746.
Vazquez, P.P., Galera, M.M., Frenich, A.G., Vidal, J.L.M., 2000. Comparison of Calibration Methods with and without Feature Selection for the Analysis of HPLC Data. Anal. Sci. 16, 49–55.
W. J. Bijlsma, J., Buttgereit, F., 2016. Adverse events of glucocorticoids during treatment of rheumatoid arthritis: lessons from cohort and registry studies: Table 1. Rheumatology 55, ii3–ii5.
Zhang, C.Y., Chang, D.L., Chen, S.L., 2011. Simultaneous Determination of Five Nonsteroidal Anti-Inflammatory Drugs and Two Glucocorticoids in Adulterated Traditional Herbal Medicines for the Treatment of Rheumatism. Anal. Lett. 44, 1769–1782.
Zhou, S., Guo, C., Shi, F., Jiang, W., Wang, L., 2016. Application of an ultrahigh-performance liquid chromatography coupled to quadrupole-orbitrap high-resolution mass spectrometry for the rapid screening, identification and quantification of illegal adulterated glucocorticoids in herbal medicines. J. Chromatogr. B 1038, 34–42.