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Abstract
RecoveryCu(II) dan Pb(II) yang sebagian besar terkandung dalam limbah cair industri, baik industri besar maupun rumah tangga telah dilakukan, salah satunya adalah dengan proses adsorpsi. Penelitian ini dilakukan studi kinetika adsorpsi Cu(II) dan Pb(II) dalam limbah cair untuk mengetahui efektivitas biosorben dari ekstrak kulit buah rambutan terhadap limbah cair yang mengandung Cu(II) dan Pb(II).Penentuan kinetika adsorpsi Cu(II) dan Pb(II) dengan menggunakan biosorben dari ekstrak kulit buah rambutan dilakukan melalui beberapa model kinetika yaitu model kinetika Langmuir-Hinshelwood,Santosa, Lagergreen dan Ho. Kinetika adsorpsi Cu(II) dan Pb(II) semuanya mengikuti model kinetika Ho, yang merupakan mekanisme kinetika orde dua semu.
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References
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References
Asuquo, E.; Martin, A.; Nzerem, P.; Siperstein, F.; Fan, X., 2017, Adsorption of Cd(II) and Pb(II) ions from aqueous solutions using mesoporous activated carbon adsorbent: Equilibrium, kinetics and characterisation studies, J. Environ. Chem. Eng., vol. 5, pp.: 679–698. DOI: 10.1016/j.jece.2016.12.043
Gupta, V. K.; Suhas, 2009, Application of low-cost adsorbents for dye removal—A review, J. Environ. Manag., vol. 90, pp.: 2313–2342. DOI: 10.1016/j.jenvman.2008.11.017
Hayati, B.; Maleki, A.; Najafi, F.; Daraei, H.; Gharibi, F.; McKay, G., 2017, Adsorption of Pb2+, Ni2+, Cu2+, Co2+ metal ions from aqueous solution by PPI/SiO2 as new high performance adsorbent: Preparation, characterization, isotherm, kinetic, thermodynamic studies, J. Mol. Liq., vol. 237, pp.: 428–436. DOI: 10.1016/j.molliq.2017.04.117
Hayati, B.; Maleki, A.; Najafi, F.; Daraei, H.; Gharibi, F.; McKay, G., 2017, Super high removal capacities of heavy metals (Pb2+ and Cu2+) using CNT dendrimer, J. Hazard. Mater., vol. 336, pp.: 146–157. DOI: 10.1016/j.jhazmat.2017.02.059
He, Y.; Wu, P.; Xiao, W.; Li, G.; Yi, J.; He, Y.; Chen, C.; Ding, P.; Duan, Y., 2019, Efficient removal of Pb(II) from aqueous solution by a novel ion imprinted magnetic biosorbent: Adsorption kinetics and mechanisms, PLoS ONE, vol. 14(3), pp: e0213377. https://doi.org/10.1371/journal.pone.0213377
Höhener, P.; Yu, X., 2012, Stable carbon and hydrogen isotope fractionation of dissolved organic groundwater pollutants by equilibrium sorption, J. Contam. Hydrol,, vol. 129–130, pp.: 54–61. DOI: 10.1016/j.jconhyd.2011.09.006
Jr., D. L. S.; Daley, J. C.; Stephens, R. L., 2013, Lead Removal by Ion Exchange, John Wiley & Sons, Inc., Hoboken.
Kavak, D., 2012, Removal of lead from aqueous solutions by precipitation statistical analysis and modeling, Desalin. Water Treat., vol. 51, pp.:1720–1726. https://doi.org/10.1080/19443994.2012.714652
Li, X.; Li, H.; Xu, X.; Guo, N.; Yuan, L.; Yu, H., 2017, Preparation of a Reduced Graphene Oxide @Stainless Steel Net Electrode and Its Applicationof Electrochemical Removal Pb(II), J. Electrochem. Soc., vol. 164(4), pp.: E71–E77. DOI: 10.1149/2.1211704jes
Limousin, G.; Gaudet, J.-P.; Charlet, L.; Szenknect, S.; Barthès, V.; Krimissa, M., 2007, Sorption isotherms: A review on physical bases, modeling and measurement, Appl. Geochem, vol. 22, pp.: 249–275. doi:10.1016/j.apgeochem.2006.09.010
Melita, L.; Popescu, M., 2008, Removal of Cr(VI) from industrial water effluents and surface waters using activated composite membranes, Journal of Membrane Science, vol. 312(1-2), pp.: 157–162. DOI: 10.1016/j.memsci.2007.12.049
Perea-Moreno, M.-A.; Sameron-Manzano, E.; Perea-Moreno, A.-J., 2019, Biomass as Renewable Energy: Worldwide Research Trends, Sustainability, vol. 11(3), 863, pp.: 1-19. https://doi.org/10.3390/su11030863
Tawinteung, N.; Parkpian, P.; DeLaune, R. D.; Jugsujinda, A., 2005, Evaluation of extraction procedures for removing lead from contaminated soil, J. Environ. Sci. Health A Tox. Hazard Subst. Environ. Eng., vol. 40(2), pp.: 385–407. DOI: 10.1081/ese-200045631
Tsai, W.-C.; de Luna, M. D. G.; Bermillo-Arriesgado, H. L. P.; Futalan, C. M.; Colades, J. I.; Wan, M.-W., 2016, Competitive Fixed-Bed Adsorption of Pb(II), Cu(II), and Ni(II) from Aqueous Solution Using Chitosan-Coated Bentonite, International Journal of Polymer Science, vol. 2016, pp.: 1-11. https://doi.org/10.1155/2016/1608939